linkedin post 2022-04-02 05:27:49

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ALCHEMY. “Once a mesocrystal is formed, it can be transformed to a mesocrystal of another mineral system by topotactic conversion under favorable conditions. The term topotaxy (Greek; "topos" = "space" and "taxis" = "in ordered manner") describes all solid state reactions that lead to a material with crystal orientations, which are correlated with crystal orientations in the initial product.” https://lnkd.in/eNACsghr View in LinkedIn
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linkedin post 2022-04-02 05:25:46

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MINIMAL ENERGY STATES. “The driving force for the geometrical alignment is the minimization of the interface mismatch energy by forming a coherent interface and reducing the exposed surface area while edge sharing is promoted by reduction of the amount of dangling unsaturated bonds along the edge, which have an inherently high chemical energy.” https://lnkd.in/eNACsghr View in LinkedIn
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linkedin post 2022-04-02 05:23:52

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GEOMETRIC CONSTRAINTS. “The fourth possibility for the formation of a mesocrystal would be a simple geometric argument. When crystalline nanoparticles grow and these nanoparticles are not spherical in shape, simple entropic arguments (known from the Onsager theory of liquid crystallinity) can explain their alignment in a constrained reaction environment upon particle growth.” https://lnkd.in/eNACsghr View in LinkedIn
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linkedin post 2022-04-02 05:23:14

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MINERAL BRIDGES. “An assembly of mineral bridge connected crystals is in fact also a single crystal. Thus, this concept is the most straightforward one among the mesocrystal formation mechanisms to explain the mutual crystallographic orientation of the nanocrystal.” https://lnkd.in/eNACsghr View in LinkedIn
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linkedin post 2022-04-03 04:51:36

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THE CORRESPONDENCE. “The smallest regular unit in such a crystal is the unit cell, which corresponds to the secondary structure in biopolymers (a-helix, B-sheet, y-turn). The interaction between several secondary structural elements of biopolymers defines the tertiary structure.” https://lnkd.in/eNACsghr View in LinkedIn
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